CorrectAs I understand it, Deluxe guests can try for the EEH VQ at 6pm even if they got a VQ at 7 or 1. (And you can also buy one ILL so a Deluxe guest could potentially ride it thrice on an EEH day.)
Each guest can get, at least try for
1 VQ
1 ILL
In addition Deluxe guests can get, or try for
Extra hours VQ
All in the same day, if offered